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This manuscript describes a simple and effective method to cyclodehydrogenate arenes using liquid alkali metals. Direct reaction between molten potassium and arenes forms 6-membered rings and zigzag edged structures within polyarenes. The approach is extended to integration of pyridinic nitrogen and 5-membered rings to arene structures and synthesis of larger, open-shell nanographenes.more » « lessFree, publicly-accessible full text available January 8, 2026
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Li, Liang; Louie, Shayan; Evans, Austin M.; Meirzadeh, Elena; Nuckolls, Colin; Venkataraman, Latha (, Journal of the American Chemical Society)
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Posey, Victoria A.; Turkel, Simon; Rezaee, Mehdi; Devarakonda, Aravind; Kundu, Asish K.; Ong, Chin Shen; Thinel, Morgan; Chica, Daniel G.; Vitalone, Rocco A.; Jing, Ran; et al (, Nature)
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Bartholomew, Amymarie K.; Meirzadeh, Elena; Stone, Ilana B.; Koay, Christie S.; Nuckolls, Colin; Steigerwald, Michael L.; Crowther, Andrew C.; Roy, Xavier (, Journal of the American Chemical Society)
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He, Shoushou; Evans, Austin M.; Meirzadeh, Elena; Han, Sae Young; Russell, Jake C.; Wiscons, Ren A.; Bartholomew, Amymarie K.; Reed, Douglas A.; Zangiabadi, Amirali; Steigerwald, Michael L.; et al (, Journal of the American Chemical Society)
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Meirzadeh, Elena; Evans, Austin M.; Rezaee, Mehdi; Milich, Milena; Dionne, Connor J.; Darlington, Thomas P.; Bao, Si Tong; Bartholomew, Amymarie K.; Handa, Taketo; Rizzo, Daniel J.; et al (, Nature)
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